• dr Sabina Jakóbczyk-Karpierz
Position: adiunkt
Unit: Instytut Nauk o Ziemi
Adress: 41-200 Sosnowiec, ul. Będzińska 60
Floor: V
Room: 516
Phone: (32) 3689 375
E-mail: sabina.jakobczyk@us.edu.pl
Publications list: Publications by CINiBA
Publications list: Publications by OPUS
Scopus Author ID: 55513502500
Publications from the Scopus database
2023
Sitek, S. S.; Janik, K.; Dąbrowska, D.; Różkowski, J.; Wojtal, G.; Mukawa, J.; Witkowski, A. Jarosław; Jakóbczyk-Karpierz, S.
Risk assessment for the prevention of managed aquifer recharge (MAR) facility failure during the operation and the expansion phases Journal Article
In: Journal of Hydrology, vol. 621, 2023, ISSN: 00221694, (1).
@article{2-s2.0-85162229004,
title = {Risk assessment for the prevention of managed aquifer recharge (MAR) facility failure during the operation and the expansion phases},
author = { S.S. Sitek and K. Janik and D. Dąbrowska and J. Różkowski and G. Wojtal and J. Mukawa and A. Jarosław Witkowski and S. Jakóbczyk-Karpierz},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85162229004&doi=10.1016%2fj.jhydrol.2023.129591&partnerID=40&md5=5b03919dc0e62351a4f849e024d847ca},
doi = {10.1016/j.jhydrol.2023.129591},
issn = {00221694},
year = {2023},
date = {2023-01-01},
journal = {Journal of Hydrology},
volume = {621},
publisher = {Elsevier B.V.},
abstract = {This comprehensive risk assessment, done for a MAR facility in Tarnów, southern Poland, covers two MAR techniques: infiltration ditches and induced bank filtration during the operation and planned potential expansion phases. Two methods were applied: the semi-quantitative risk assessment matrix and the probabilistic risk assessment – fault tree analysis (PRA-FTA), and their advantages and limitations analysed. Both methods examine a range of technical and non-technical risks that may pose a threat to the efficient functioning of the MAR facility in Tarnów, which supplies about 25% of the city's population with drinking water. It was found that 34 of the 65 risks analysed could pose a low to high risk for the Świerczków well field. The predominant risks potentially reducing MAR efficiency or leading to MAR failure are technical ones. According to the PRA-FTA method, if no preventive measures are taken, there is a 99.5 and 99.3% probability of the MAR system failing during the operational and expansion phases, respectively. The results indicate that the most serious risk is associated with the insufficient initial removal from the recharge river water of suspended solids, which clog infiltration ditches. The risks scored as medium relate to the threat of groundwater inflow from an extensive industrial zone, lying to the east of the well field, and to climate change negatively affecting the quantity of groundwater resources. This is the first example in Poland of a risk assessment for an existing MAR facility and its expansion, based on a broad spectrum of technical and non-technical risks present at the Świerczków well field, using two methods: the risk assessment matrix and PRA-FTA. This case study is a practical example of how to perform a risk analysis for a MAR site. It can make an important contribution to existing knowledge in this field and enrich the subject literature, a particularly relevant aspect given the widespread use of MAR techniques in Central Europe for the supply of drinking water to the public. © 2023 Elsevier B.V.},
note = {1},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
This comprehensive risk assessment, done for a MAR facility in Tarnów, southern Poland, covers two MAR techniques: infiltration ditches and induced bank filtration during the operation and planned potential expansion phases. Two methods were applied: the semi-quantitative risk assessment matrix and the probabilistic risk assessment – fault tree analysis (PRA-FTA), and their advantages and limitations analysed. Both methods examine a range of technical and non-technical risks that may pose a threat to the efficient functioning of the MAR facility in Tarnów, which supplies about 25% of the city's population with drinking water. It was found that 34 of the 65 risks analysed could pose a low to high risk for the Świerczków well field. The predominant risks potentially reducing MAR efficiency or leading to MAR failure are technical ones. According to the PRA-FTA method, if no preventive measures are taken, there is a 99.5 and 99.3% probability of the MAR system failing during the operational and expansion phases, respectively. The results indicate that the most serious risk is associated with the insufficient initial removal from the recharge river water of suspended solids, which clog infiltration ditches. The risks scored as medium relate to the threat of groundwater inflow from an extensive industrial zone, lying to the east of the well field, and to climate change negatively affecting the quantity of groundwater resources. This is the first example in Poland of a risk assessment for an existing MAR facility and its expansion, based on a broad spectrum of technical and non-technical risks present at the Świerczków well field, using two methods: the risk assessment matrix and PRA-FTA. This case study is a practical example of how to perform a risk analysis for a MAR site. It can make an important contribution to existing knowledge in this field and enrich the subject literature, a particularly relevant aspect given the widespread use of MAR techniques in Central Europe for the supply of drinking water to the public. © 2023 Elsevier B.V.
2022
Jakóbczyk-Karpierz, S.; Ślósarczyk, K.
In: Journal of Hydrology, vol. 612, 2022, ISSN: 00221694, (2).
@article{2-s2.0-85135370062,
title = {Isotopic signature of anthropogenic sources of groundwater contamination with sulfate and its application to groundwater in a heavily urbanized and industrialized area (Upper Silesia, Poland)},
author = { S. Jakóbczyk-Karpierz and K. Ślósarczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85135370062&doi=10.1016%2fj.jhydrol.2022.128255&partnerID=40&md5=d7dd1ef67efd7760e5cb205a2b7a4bd0},
doi = {10.1016/j.jhydrol.2022.128255},
issn = {00221694},
year = {2022},
date = {2022-01-01},
journal = {Journal of Hydrology},
volume = {612},
publisher = {Elsevier B.V.},
abstract = {Isotopic signatures of anthropogenic sulfate sources within the Upper Silesian urban area (southern Poland) were investigated to increase the reliability of the origin assessment of groundwater contaminants. To analyze δ34S and δ18O in sulfate, 64 samples were collected, representing several sulfate sources: synthetic and organic fertilizers, raw and treated wastewater, mine water, leachate from landfills, mine heaps, and industrial waste dumps. Additionally, 10 surface water samples were taken from contaminated rivers regarded as potential groundwater pollution sources. Results of δ34S and δ18O in sulfate derived from anthropogenic sources were compared with literature data, which indicated significant discrepancies for some contamination sources. The results were applied to assess SO42- origin in groundwater samples from the Gliwice aquifer. Apart from the δ34S and δ18O data, the study included measurements of major ions, inorganic nitrogen forms, trichloroethene and tetrachloroethene in groundwater. Isotopic analyses of river water samples confirmed the impact of urbanized and industrialized areas on surface water pollution and possible influence on groundwater contamination. The values of δ34S and δ18O similar to wastewater were reported for most groundwater samples from the Gliwice carbonate aquifer. Groundwater contamination was also manifested by higher values of electrical conductivity and concentrations of chloride, sodium, trichloroethene and tetrachloroethene. The comparison of recent isotopic data on SO42- sources with literature values clearly shows that it is very important to investigate local potential contamination sources to increase their reliability in determining the source of groundwater or river water pollution. © 2022 The Author(s)},
note = {2},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Isotopic signatures of anthropogenic sulfate sources within the Upper Silesian urban area (southern Poland) were investigated to increase the reliability of the origin assessment of groundwater contaminants. To analyze δ34S and δ18O in sulfate, 64 samples were collected, representing several sulfate sources: synthetic and organic fertilizers, raw and treated wastewater, mine water, leachate from landfills, mine heaps, and industrial waste dumps. Additionally, 10 surface water samples were taken from contaminated rivers regarded as potential groundwater pollution sources. Results of δ34S and δ18O in sulfate derived from anthropogenic sources were compared with literature data, which indicated significant discrepancies for some contamination sources. The results were applied to assess SO42- origin in groundwater samples from the Gliwice aquifer. Apart from the δ34S and δ18O data, the study included measurements of major ions, inorganic nitrogen forms, trichloroethene and tetrachloroethene in groundwater. Isotopic analyses of river water samples confirmed the impact of urbanized and industrialized areas on surface water pollution and possible influence on groundwater contamination. The values of δ34S and δ18O similar to wastewater were reported for most groundwater samples from the Gliwice carbonate aquifer. Groundwater contamination was also manifested by higher values of electrical conductivity and concentrations of chloride, sodium, trichloroethene and tetrachloroethene. The comparison of recent isotopic data on SO42- sources with literature values clearly shows that it is very important to investigate local potential contamination sources to increase their reliability in determining the source of groundwater or river water pollution. © 2022 The Author(s)
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Witkowski, A. J.
In: Water (Switzerland), vol. 14, no. 6, 2022, ISSN: 20734441, (1).
@article{2-s2.0-85126358541,
title = {Identification of Water Contamination Sources Using Hydrochemical and Isotopic Studies—The Kozłowa Góra Reservoir Catchment Area (Southern Poland)},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz and A.J. Witkowski},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85126358541&doi=10.3390%2fw14060846&partnerID=40&md5=e498a1a5d4ebf0e3031382e0676baf5d},
doi = {10.3390/w14060846},
issn = {20734441},
year = {2022},
date = {2022-01-01},
journal = {Water (Switzerland)},
volume = {14},
number = {6},
publisher = {MDPI},
abstract = {The application of combined research methods, such as hydrochemical and isotopic anal-yses, facilitates understanding of the origin of water constituents and migration of contaminants in the aquatic environment. The presented study attempts to identify contamination sources affecting water quality within the Kozłowa Góra reservoir catchment area (southern Poland). A total of 100 water samples were collected from surface water (the Brynica river; streams; and the reservoir) and groundwater (a Quarternary aquifer) in four time periods. During fieldwork, the physicochemical parameters were measured (temperature; pH; electrical conductivity; redox potential; and dissolved oxygen). The chemical analysis included the determination of major ions (HCO3−; SO42−; Cl−; Ca2+; Mg2+; Na+; and K+), nutrients (NO3−; NO2−; NH4+; and PO43−), and total organic carbon. The study was complemented by isotopic analysis of sulphur and oxygen in sulphate, which enabled a more pre-cise identification of stressors affecting water quality in different parts of the catchment area. Chemical and isotopic results (δ34S = 4.38–13.99‰; δ18O 3.59–13.30‰) revealed that wastewater discharges and agricultural activities have a significant influence on the chemistry of the Brynica River and other streams. At some sampling points, a lower quality of water was manifested by elevated concentrations of NO3− (up to 22.6 mg/L) and several other ions (e.g.; up to 114 mg/L for Cl−; up to 51.52 mg/L for NH4+; and 12.5 mg/L for PO43−). The quality of groundwater was deteriorated mainly by infiltration of sewage from leaky septic tanks. The level of groundwater contamination varied depending on the location, as higher concentrations of major ions and values of electrical conductivity were observed in residential areas. The Brynica river, streams, and groundwater recharge the drinking water reservoir, and thus its quality depends on these sources. A dilution of water and the presence of biochemical processes led to a reduction of contaminant concentrations in the Kozłowa Góra reservoir (down to 3.5 mg/L for NO3−; 32 mg/L for Cl−; 0.21 mg/L for NH4+; and <0.05 mg/L for PO43−) compared to water in the river and streams supplying the reservoir. The study revealed the role of wastewater discharge and agricultural activities in the evolution of surface water chemistry. The results will be used in further research on the origin and migration of other substances in water, including microcontaminants. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.},
note = {1},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The application of combined research methods, such as hydrochemical and isotopic anal-yses, facilitates understanding of the origin of water constituents and migration of contaminants in the aquatic environment. The presented study attempts to identify contamination sources affecting water quality within the Kozłowa Góra reservoir catchment area (southern Poland). A total of 100 water samples were collected from surface water (the Brynica river; streams; and the reservoir) and groundwater (a Quarternary aquifer) in four time periods. During fieldwork, the physicochemical parameters were measured (temperature; pH; electrical conductivity; redox potential; and dissolved oxygen). The chemical analysis included the determination of major ions (HCO3−; SO42−; Cl−; Ca2+; Mg2+; Na+; and K+), nutrients (NO3−; NO2−; NH4+; and PO43−), and total organic carbon. The study was complemented by isotopic analysis of sulphur and oxygen in sulphate, which enabled a more pre-cise identification of stressors affecting water quality in different parts of the catchment area. Chemical and isotopic results (δ34S = 4.38–13.99‰; δ18O 3.59–13.30‰) revealed that wastewater discharges and agricultural activities have a significant influence on the chemistry of the Brynica River and other streams. At some sampling points, a lower quality of water was manifested by elevated concentrations of NO3− (up to 22.6 mg/L) and several other ions (e.g.; up to 114 mg/L for Cl−; up to 51.52 mg/L for NH4+; and 12.5 mg/L for PO43−). The quality of groundwater was deteriorated mainly by infiltration of sewage from leaky septic tanks. The level of groundwater contamination varied depending on the location, as higher concentrations of major ions and values of electrical conductivity were observed in residential areas. The Brynica river, streams, and groundwater recharge the drinking water reservoir, and thus its quality depends on these sources. A dilution of water and the presence of biochemical processes led to a reduction of contaminant concentrations in the Kozłowa Góra reservoir (down to 3.5 mg/L for NO3−; 32 mg/L for Cl−; 0.21 mg/L for NH4+; and <0.05 mg/L for PO43−) compared to water in the river and streams supplying the reservoir. The study revealed the role of wastewater discharge and agricultural activities in the evolution of surface water chemistry. The results will be used in further research on the origin and migration of other substances in water, including microcontaminants. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
2021
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Różkowski, J.; Witkowski, A. J.
Occurrence of pharmaceuticals and personal care products in the water environment of Poland: A review Journal Article
In: Water (Switzerland), vol. 13, no. 16, 2021, ISSN: 20734441, (5).
@article{2-s2.0-85113770401,
title = {Occurrence of pharmaceuticals and personal care products in the water environment of Poland: A review},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz and J. Różkowski and A.J. Witkowski},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85113770401&doi=10.3390%2fw13162283&partnerID=40&md5=dd9d80ae30e1ef5da6bad75f60157b94},
doi = {10.3390/w13162283},
issn = {20734441},
year = {2021},
date = {2021-01-01},
journal = {Water (Switzerland)},
volume = {13},
number = {16},
publisher = {MDPI AG},
abstract = {The issue of pharmaceuticals and personal care products (PPCPs) in the water environment has gained increasing interest worldwide. To determine the nature and extent of this problem for Poland, this paper presents a review of research on the presence of PPCPs in Poland, looking at results for different water samples, including wastewater (before and after treatment), landfill leachate, surface water (standing water bodies and rivers), seawater, groundwater and drinking water. The review is based on over 50 scientific articles and dissertations referring to studies of PPCPs. It also briefly outlines possible sources and the fate of PPCPs in the aquatic environment. The review of Polish research has revealed that studies have previously covered at least 39 PPCP groups (270 compounds in total). These studies focused mainly on wastewater and rivers, and only a few concerned landfill leachate and seawater. They most often reported on nonsteroidal anti-inflammatory drugs and antibiotics. The highest concentrations of the analysed PPCPs were found mainly in raw wastewater (e.g.; naproxen; up to 551;960 ng/L), but they were also occasionally found in surface water (e.g.; azithromycin; erythromycin; irbesartan and metoprolol) and in groundwater (e.g.; N;N-diethyl-meta-toluamide; known as DEET; up to 17;280 ng/L). Extremely high concentrations of bisphenol A (up to 2;202;000 ng/L) and diclofenac (up to 108;340 ng/L) were found in landfill leachate. Although numerous substances have been detected, PPCPs are still not monitored regularly, which makes it difficult to obtain a clear understanding of their incidence in the water environment. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.},
note = {5},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The issue of pharmaceuticals and personal care products (PPCPs) in the water environment has gained increasing interest worldwide. To determine the nature and extent of this problem for Poland, this paper presents a review of research on the presence of PPCPs in Poland, looking at results for different water samples, including wastewater (before and after treatment), landfill leachate, surface water (standing water bodies and rivers), seawater, groundwater and drinking water. The review is based on over 50 scientific articles and dissertations referring to studies of PPCPs. It also briefly outlines possible sources and the fate of PPCPs in the aquatic environment. The review of Polish research has revealed that studies have previously covered at least 39 PPCP groups (270 compounds in total). These studies focused mainly on wastewater and rivers, and only a few concerned landfill leachate and seawater. They most often reported on nonsteroidal anti-inflammatory drugs and antibiotics. The highest concentrations of the analysed PPCPs were found mainly in raw wastewater (e.g.; naproxen; up to 551;960 ng/L), but they were also occasionally found in surface water (e.g.; azithromycin; erythromycin; irbesartan and metoprolol) and in groundwater (e.g.; N;N-diethyl-meta-toluamide; known as DEET; up to 17;280 ng/L). Extremely high concentrations of bisphenol A (up to 2;202;000 ng/L) and diclofenac (up to 108;340 ng/L) were found in landfill leachate. Although numerous substances have been detected, PPCPs are still not monitored regularly, which makes it difficult to obtain a clear understanding of their incidence in the water environment. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
2020
Jakóbczyk-Karpierz, S.; Ślósarczyk, K.; Sitek, S. S.
In: Applied Geochemistry, vol. 118, 2020, ISSN: 08832927, (7).
@article{2-s2.0-85084362774,
title = {Tracing multiple sources of groundwater pollution in a complex carbonate aquifer (Tarnowskie Góry, southern Poland) using hydrogeochemical tracers, TCE, PCE, SF6 and CFCs},
author = { S. Jakóbczyk-Karpierz and K. Ślósarczyk and S.S. Sitek},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85084362774&doi=10.1016%2fj.apgeochem.2020.104623&partnerID=40&md5=4f7f9838d29344041202498c40263491},
doi = {10.1016/j.apgeochem.2020.104623},
issn = {08832927},
year = {2020},
date = {2020-01-01},
urldate = {2020-01-01},
journal = {Applied Geochemistry},
volume = {118},
publisher = {Elsevier Ltd},
abstract = {A comprehensive study on the sources of groundwater contamination in the Triassic carbonate aquifer, southern Poland, was conducted. The Gliwice aquifer is an important source of potable water in the Silesia region, the most industrialized part of Poland. Groundwater quality has been deteriorating over the last decades, which encouraged researchers to undertake comprehensive study to identify the sources and fates of the observed pollution. The presented study comprised analyses of major and minor ions, trichloroethylene (TCE) and tetrachloroethylene (PCE), CFC-11, CFC-12, SF6, Ne and Ar in groundwater. The results showed that shallow groundwater within the Tarnowskie Góry town, located in the recharge zone of the aquifer, was more contaminated than groundwater abstracted from deeper part of the aquifer within the town, as well as groundwater located downgradient. A contamination plume of boron indicated an impact of the closed chemical plant, operating in the 20th century. Groundwater in the vicinity of the chemical plant was significantly altered, which was manifested by elevated concentrations of Cl−, SO4 2-, Na+, total Fe and Mn. The study revealed groundwater contamination with CFC-11 and CFC-12. Comparison of concentrations obtained in two field campaigns (in 2010 and 2015) showed an increase in the extent of pollution plumes. The third analysed gaseous tracer, SF6, did not appear to come from non-atmospheric sources, therefore, it was possible to calculate groundwater age using lumped parameter models. The results showed relatively young ages of the analysed groundwater samples, from 4 to 5 to 30–50 years. The youngest groundwater were found close to the Drama River, suggesting infiltration of the surface water into the carbonate aquifer. This feature of the river was confirmed by the observation of TCE and PCE concentrations in groundwater. Central part of the Tarnowskie Góry town was a source area for TCE and PCE contamination. Two directions of pollutants migration were observed, one of them was induced by the drainage of the historic ore mine and subsequently the Drama River – recipient of water coming from the mine drainage. © 2020 Elsevier Ltd},
note = {7},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
A comprehensive study on the sources of groundwater contamination in the Triassic carbonate aquifer, southern Poland, was conducted. The Gliwice aquifer is an important source of potable water in the Silesia region, the most industrialized part of Poland. Groundwater quality has been deteriorating over the last decades, which encouraged researchers to undertake comprehensive study to identify the sources and fates of the observed pollution. The presented study comprised analyses of major and minor ions, trichloroethylene (TCE) and tetrachloroethylene (PCE), CFC-11, CFC-12, SF6, Ne and Ar in groundwater. The results showed that shallow groundwater within the Tarnowskie Góry town, located in the recharge zone of the aquifer, was more contaminated than groundwater abstracted from deeper part of the aquifer within the town, as well as groundwater located downgradient. A contamination plume of boron indicated an impact of the closed chemical plant, operating in the 20th century. Groundwater in the vicinity of the chemical plant was significantly altered, which was manifested by elevated concentrations of Cl−, SO4 2-, Na+, total Fe and Mn. The study revealed groundwater contamination with CFC-11 and CFC-12. Comparison of concentrations obtained in two field campaigns (in 2010 and 2015) showed an increase in the extent of pollution plumes. The third analysed gaseous tracer, SF6, did not appear to come from non-atmospheric sources, therefore, it was possible to calculate groundwater age using lumped parameter models. The results showed relatively young ages of the analysed groundwater samples, from 4 to 5 to 30–50 years. The youngest groundwater were found close to the Drama River, suggesting infiltration of the surface water into the carbonate aquifer. This feature of the river was confirmed by the observation of TCE and PCE concentrations in groundwater. Central part of the Tarnowskie Góry town was a source area for TCE and PCE contamination. Two directions of pollutants migration were observed, one of them was induced by the drainage of the historic ore mine and subsequently the Drama River – recipient of water coming from the mine drainage. © 2020 Elsevier Ltd
Różkowski, J.; Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Rubin, H.
Polish Geological Institute, vol. 68, no. 4, 2020, ISSN: 00332151, (1).
@proceedings{2-s2.0-85096340252,
title = {Occurrence, sources of PAHs, and groundwater protection against pollution in the Cieszyńskie ródła Tufowe Natura 2000 area [Wysţpowanie i geneza WWA w wodach podziemnych obszaru Natura 2000 Cieszyńskie ródła Tufowe oraz ochrona tych wód przed zanieczyszczeniem]},
author = { J. Różkowski and K. Ślósarczyk and S. Jakóbczyk-Karpierz and H. Rubin},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85096340252&doi=10.7306%2f2020.12&partnerID=40&md5=a390b2d497b474260b8fde3185ca31fb},
doi = {10.7306/2020.12},
issn = {00332151},
year = {2020},
date = {2020-01-01},
journal = {Przeglad Geologiczny},
volume = {68},
number = {4},
pages = {249-255},
publisher = {Polish Geological Institute},
abstract = {The paper deals with the problem of groundwater pollution with polycyclic aromatic hydrocarbons (PAHs) in the "Cieszyńskie ródła Tufowe " Natura 2000 area. The concentration of 16 PAHs was measured with the use of the GC-MS method in seven water samples collected from the area of four enclaves belonging to the nature reserve. The results of analyses were compared with both the hydrogeochemical background and the limit value of PAHs concentration in drinking water, defined in the Regulation of the Minister for Health. Additionally, in order to determine the origin of contamination, PAH ratios for selected compounds were calculated. The paper also highlights the importance of the PAHs monitoring in groundwater. © 2020 Polish Geological Institute. All rights reserved.},
note = {1},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The paper deals with the problem of groundwater pollution with polycyclic aromatic hydrocarbons (PAHs) in the "Cieszyńskie ródła Tufowe " Natura 2000 area. The concentration of 16 PAHs was measured with the use of the GC-MS method in seven water samples collected from the area of four enclaves belonging to the nature reserve. The results of analyses were compared with both the hydrogeochemical background and the limit value of PAHs concentration in drinking water, defined in the Regulation of the Minister for Health. Additionally, in order to determine the origin of contamination, PAH ratios for selected compounds were calculated. The paper also highlights the importance of the PAHs monitoring in groundwater. © 2020 Polish Geological Institute. All rights reserved.
2019
Jakóbczyk-Karpierz, S.; Ślósarczyk, K.
International Multidisciplinary Scientific Geoconference, vol. 19, no. 1.2, 2019, ISSN: 13142704.
@proceedings{2-s2.0-85073698937,
title = {Application of geochemical and isotopic study (δ15nno3, δ18ono3, δ34 sso4, δ18 oso4) to assess the extent of human impact on groundwater quality in the area of kuŹnica warĘŻyŃska reservoir (southern poland)},
author = { S. Jakóbczyk-Karpierz and K. Ślósarczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073698937&doi=10.5593%2fsgem2019%2f1.2%2fS02.010&partnerID=40&md5=f5320fc6bab350eeb98828a543ef4ae5},
doi = {10.5593/sgem2019/1.2/S02.010},
issn = {13142704},
year = {2019},
date = {2019-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {19},
number = {1.2},
pages = {71-78},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {The Kuźnica Warężyńska surface reservoir with an area of 5.6 km2 is located in the Silesian district, southern Poland. It was established in 2006 as a result of flooding of a sand pit after over 40 years of mine operation. Currently, it has various functions, the most important of which are flood control and recreational. The long-term dewatering of the pit and its subsequent flooding caused significant changes in the geochemical conditions in the Quaternary aquifer composed of sands and gravels. In addition, numerous buildings around the reservoir do not have a sewage network, which may affect the concentration of such constituents of groundwater as inorganic nitrogen forms, sulphates, bicarbonates or chlorides. In 2018, studies on the chemistry of groundwater from the Quaternary aquifer were carried out around the reservoir. The isotopic composition of nitrates and sulphates in groundwater samples from three selected piezometers was also determined. The results indicate a high diversity of the chemical composition of groundwater around the reservoir. Water electrical conductivity varies in the range 243-1101 μS/cm, nitrate concentrations vary from 0.25 to 57.2 mg/L, bicarbonate – from 24.4 to 396.6 mg/L, Fe2+ from 0 to 3.0 mg/L and Mn2+ from 0.01 to 0.69 mg/L, while sulphate concentrations are more uniform around the reservoir (49-89 mg/L). The results of isotopic studies of S and O in sulphates indicate the origin of sulphates from the oxidation of sulphide minerals and from municipal sewage. Isotopic studies of nitrates suggest their origin from natural fertilizers or municipal sewage. Therefore, it seems that the dominant factor determining the deterioration of groundwater quality is unregulated sewage management around the reservoir. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The Kuźnica Warężyńska surface reservoir with an area of 5.6 km2 is located in the Silesian district, southern Poland. It was established in 2006 as a result of flooding of a sand pit after over 40 years of mine operation. Currently, it has various functions, the most important of which are flood control and recreational. The long-term dewatering of the pit and its subsequent flooding caused significant changes in the geochemical conditions in the Quaternary aquifer composed of sands and gravels. In addition, numerous buildings around the reservoir do not have a sewage network, which may affect the concentration of such constituents of groundwater as inorganic nitrogen forms, sulphates, bicarbonates or chlorides. In 2018, studies on the chemistry of groundwater from the Quaternary aquifer were carried out around the reservoir. The isotopic composition of nitrates and sulphates in groundwater samples from three selected piezometers was also determined. The results indicate a high diversity of the chemical composition of groundwater around the reservoir. Water electrical conductivity varies in the range 243-1101 μS/cm, nitrate concentrations vary from 0.25 to 57.2 mg/L, bicarbonate – from 24.4 to 396.6 mg/L, Fe2+ from 0 to 3.0 mg/L and Mn2+ from 0.01 to 0.69 mg/L, while sulphate concentrations are more uniform around the reservoir (49-89 mg/L). The results of isotopic studies of S and O in sulphates indicate the origin of sulphates from the oxidation of sulphide minerals and from municipal sewage. Isotopic studies of nitrates suggest their origin from natural fertilizers or municipal sewage. Therefore, it seems that the dominant factor determining the deterioration of groundwater quality is unregulated sewage management around the reservoir. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Rubin, H.; Różkowski, J.; Magiera, T.
International Multidisciplinary Scientific Geoconference, vol. 19, no. 1.2, 2019, ISSN: 13142704.
@proceedings{2-s2.0-85073695832,
title = {Seasonal variation in contamination and sources of polycyclic aromatic hydrocarbons in the cieszyn tufa spring water (Southern poland)},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz and H. Rubin and J. Różkowski and T. Magiera},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073695832&doi=10.5593%2fsgem2019%2f1.2%2fS02.060&partnerID=40&md5=7dd51ab551d5e89a296fa39e1ef10e58},
doi = {10.5593/sgem2019/1.2/S02.060},
issn = {13142704},
year = {2019},
date = {2019-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {19},
number = {1.2},
pages = {469-476},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {The Cieszyn Tufa Springs is a special area of conservation located in the Western Carpathians (southern Poland). The main subjects of protection are springs that outflow from the contact zone between Cretaceous limestones and slates. Due to a high vulnerability of shallow aquifers within the area of Cieszyn Foothills as well as urbanization and highly-developed industry of the Silesia region, a wide range of contaminants is detected in the spring water. Although microcomponents present in water of the mentioned area are often of geogenic origin, some micro-organic compounds, including polycyclic aromatic hydrocarbons (PAHs), may occur as a result of human activities. In order to quantify PAHs in water from the springs and streams in the area of the Cieszyn Tufa Springs, 4 field campaigns were conducted in summer and autumn of 2017. The concentrations of 16 PAHs were determined using the GC-MS method. The total concentration of examined PAHs observed throughout the considered period ranged between 0.079 and 1.3938 µg/L. The obtained results revealed seasonal variability manifested by the increase in PAHs concentrations in autumn. In a few samples, the sum of the concentrations of 4 PAHs (benzo(b)fluoranthene; benzo(k)fluoranthene; benzo(ghi)perylene and indeno(1;2;3-cd)pyrene) exceeded the drinking water limit (0.1 µg/L). In addition, an attempt has been made to identify the source of target compounds using PAH diagnostic ratios. The comparison of PAHs’ ratios allows to make an assumption that a large proportion of tested compounds derives from car exhausts and low-stack emission and they probably were introduced to spring water through the deposition of air pollutants. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The Cieszyn Tufa Springs is a special area of conservation located in the Western Carpathians (southern Poland). The main subjects of protection are springs that outflow from the contact zone between Cretaceous limestones and slates. Due to a high vulnerability of shallow aquifers within the area of Cieszyn Foothills as well as urbanization and highly-developed industry of the Silesia region, a wide range of contaminants is detected in the spring water. Although microcomponents present in water of the mentioned area are often of geogenic origin, some micro-organic compounds, including polycyclic aromatic hydrocarbons (PAHs), may occur as a result of human activities. In order to quantify PAHs in water from the springs and streams in the area of the Cieszyn Tufa Springs, 4 field campaigns were conducted in summer and autumn of 2017. The concentrations of 16 PAHs were determined using the GC-MS method. The total concentration of examined PAHs observed throughout the considered period ranged between 0.079 and 1.3938 µg/L. The obtained results revealed seasonal variability manifested by the increase in PAHs concentrations in autumn. In a few samples, the sum of the concentrations of 4 PAHs (benzo(b)fluoranthene; benzo(k)fluoranthene; benzo(ghi)perylene and indeno(1;2;3-cd)pyrene) exceeded the drinking water limit (0.1 µg/L). In addition, an attempt has been made to identify the source of target compounds using PAH diagnostic ratios. The comparison of PAHs’ ratios allows to make an assumption that a large proportion of tested compounds derives from car exhausts and low-stack emission and they probably were introduced to spring water through the deposition of air pollutants. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.; Rubin, H.; Kowalczyk, A.; Witkowski, A. J.
International Multidisciplinary Scientific Geoconference, vol. 19, no. 1.2, 2019, ISSN: 13142704.
@proceedings{2-s2.0-85073686617,
title = {Isotopic approach to identification of sulphate origin in the triassic aquifer in recharge area of the Łazy bŁĘdowskie well field (Southern poland)},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz and H. Rubin and A. Kowalczyk and A.J. Witkowski},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073686617&doi=10.5593%2fsgem2019%2f1.2%2fS02.046&partnerID=40&md5=b19dc34325f8a6880abe555e5b073702},
doi = {10.5593/sgem2019/1.2/S02.046},
issn = {13142704},
year = {2019},
date = {2019-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {19},
number = {1.2},
pages = {361-368},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {The Łazy Błędowskie well field located in the area of the Upper Silesia (southern Poland) abstracts water from the Triassic carbonate aquifer. The aquifer is additionally heavily drained by the Zn-Pb ore mines. Due to a deterioration of groundwater quality, caused mainly by sulphate concentration reaching 317 mg/L, most of the wells have been closed and currently only 2 wells are exploited. Sulphates origin in water has been a concern issue of many researchers. However, there are difficulties in identification of sulphates origin in groundwater influenced by severe anthropogenic transformation and negative impacts of various sources of contamination. In order to determine sulphates origin in groundwater, both chemical and isotopic studies were carried out. Analyses of isotopic composition of sulphates (δ34S and δ18 O) were conducted for 5 groundwater samples taken from 3 abstraction wells and 2 observation wells, all of them located within the capture zone to the well field. Additional sample represented sewage from a cocking plant. In addition, archival data on isotopic signature of sulphates in the Triassic aquifer in the study area was used to support the interpretation. The analysis of recent and archival results of isotopic study revealed diversity in sulphates origin in the study area depending on the location of the well, its discharge rate as well as the land use type in the recharge area. The main source of sulphates is oxidation of sulphide minerals present in the Triassic carbonate deposits. Another source of sulphates might be gypsum dissolution that occur locally within the Triassic rocks. In some cases, it was found that a significant proportion of sulphates is of anthropogenic origin: natural and artificial fertilisers, municipal and industrial waste water as well as pollution from atmospheric precipitation. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The Łazy Błędowskie well field located in the area of the Upper Silesia (southern Poland) abstracts water from the Triassic carbonate aquifer. The aquifer is additionally heavily drained by the Zn-Pb ore mines. Due to a deterioration of groundwater quality, caused mainly by sulphate concentration reaching 317 mg/L, most of the wells have been closed and currently only 2 wells are exploited. Sulphates origin in water has been a concern issue of many researchers. However, there are difficulties in identification of sulphates origin in groundwater influenced by severe anthropogenic transformation and negative impacts of various sources of contamination. In order to determine sulphates origin in groundwater, both chemical and isotopic studies were carried out. Analyses of isotopic composition of sulphates (δ34S and δ18 O) were conducted for 5 groundwater samples taken from 3 abstraction wells and 2 observation wells, all of them located within the capture zone to the well field. Additional sample represented sewage from a cocking plant. In addition, archival data on isotopic signature of sulphates in the Triassic aquifer in the study area was used to support the interpretation. The analysis of recent and archival results of isotopic study revealed diversity in sulphates origin in the study area depending on the location of the well, its discharge rate as well as the land use type in the recharge area. The main source of sulphates is oxidation of sulphide minerals present in the Triassic carbonate deposits. Another source of sulphates might be gypsum dissolution that occur locally within the Triassic rocks. In some cases, it was found that a significant proportion of sulphates is of anthropogenic origin: natural and artificial fertilisers, municipal and industrial waste water as well as pollution from atmospheric precipitation. © 2019, International Multidisciplinary Scientific Geoconference. All rights reserved.
Sitek, S. S.; Nowacka, S.; Jakóbczyk-Karpierz, S.
International Multidisciplinary Scientific Geoconference, vol. 19, no. 3.1, 2019, ISSN: 13142704.
@proceedings{2-s2.0-85073393268,
title = {Modeling of contamination transport released from old municipal solid waste landfill site: A case study, southern Poland},
author = { S.S. Sitek and S. Nowacka and S. Jakóbczyk-Karpierz},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073393268&doi=10.5593%2fsgem2019%2f3.1%2fS12.049&partnerID=40&md5=35ce750160a151f75fa66130ab682f83},
doi = {10.5593/sgem2019/3.1/S12.049},
issn = {13142704},
year = {2019},
date = {2019-01-01},
urldate = {2019-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {19},
number = {3.1},
pages = {379-386},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {The municipal solid waste landfill in Tychy, southern Poland consists of three sites, the old one, closed in 1994, and two others still being in use. The old part of the landfill has neither any bottom liner nor any leachate collection and treatment system. Moreover, the bottom of the closed site in the northern part is continuously above the groundwater table, therefore, pollution can easily release into groundwater causing deterioration of groundwater quality and the nearby river nearby. In order to assess the impact and fate of the pollution in groundwater environment and to estimate the spatial size of the contamination plume in the Quaternary sandy aquifer, the transient transport model was designed based on the steady-state flow model, calibrated for the year 2016. Boron was chosen for single-species transient mass transport model. The obtained results indicate that the contamination plume migrates towards the Gostynia river along the main groundwater flow direction. The highest concentration of boron, about 20 mg/dm3, is recorded at the northern part of the landfill site. The contamination plume migrating to the south quickly dilutes reaching the boron concentration lower than 2 mg/dm3 in groundwater close to the Gostynia river. The size of the pollution plume reaches about 1,100 m in length and an average of 225 m in width. With the assumed supply of pollutants to the aquifer at the level of 2016, the amount of boron washed-out from the old landfill site entering the Gostynia river within 20 years will be about 1.4 tons. © SGEM2019.},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
The municipal solid waste landfill in Tychy, southern Poland consists of three sites, the old one, closed in 1994, and two others still being in use. The old part of the landfill has neither any bottom liner nor any leachate collection and treatment system. Moreover, the bottom of the closed site in the northern part is continuously above the groundwater table, therefore, pollution can easily release into groundwater causing deterioration of groundwater quality and the nearby river nearby. In order to assess the impact and fate of the pollution in groundwater environment and to estimate the spatial size of the contamination plume in the Quaternary sandy aquifer, the transient transport model was designed based on the steady-state flow model, calibrated for the year 2016. Boron was chosen for single-species transient mass transport model. The obtained results indicate that the contamination plume migrates towards the Gostynia river along the main groundwater flow direction. The highest concentration of boron, about 20 mg/dm3, is recorded at the northern part of the landfill site. The contamination plume migrating to the south quickly dilutes reaching the boron concentration lower than 2 mg/dm3 in groundwater close to the Gostynia river. The size of the pollution plume reaches about 1,100 m in length and an average of 225 m in width. With the assumed supply of pollutants to the aquifer at the level of 2016, the amount of boron washed-out from the old landfill site entering the Gostynia river within 20 years will be about 1.4 tons. © SGEM2019.
2018
Ślósarczyk, K.; Jakóbczyk-Karpierz, S.
In: Przeglad Geologiczny, vol. 66, no. 8, pp. 495-502, 2018, ISSN: 00332151.
@article{2-s2.0-85055270039,
title = {Application of sulfate isotope studies and geochemical modeling in determining processes affecting groundwater chemistry in the Gliwice- Łabedy well-field area [Wykorzystanie modelowania geochemicznego oraz badań izotopowych siarczanów do identyfikacji procesów ksztaltujqcych skład chemiczny wód podziemnych ujecia Gliwice-Łabedy]},
author = { K. Ślósarczyk and S. Jakóbczyk-Karpierz},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85055270039&doi=10.7306%2f2018.3&partnerID=40&md5=3dfca7bfc873a344539e29b5521c1153},
doi = {10.7306/2018.3},
issn = {00332151},
year = {2018},
date = {2018-01-01},
journal = {Przeglad Geologiczny},
volume = {66},
number = {8},
pages = {495-502},
publisher = {Polish Geological Institute},
abstract = {In order to determine geochemical processes affecting chemical composition of groundwater in the Gliwice- Łabedy well-field area two research methods were applied. Chemical analysis allowed us to assess the quality of groundwater in the Triassic karst-fractured-porous aquifer of the southwestern part of the major groundwater basin no. 330. The chemical composition of groundwater is distinguished by spatial heterogeneity highlighted by higher mineralization and concentrations of individual ions in the western area. In addition, all samples collected in 2016 were analyzed for the δ35S and δ18O to identify sources of sulfates in the waters examined. The study revealed a different origin of these ions depending on location of the wells sampled. The results of chemical analysis and archival data allowed for application of geochemical modeling in identification of processes taking part in groundwater chemistry evolution. Simulations of processes controlling water chemistry within the Triassic aquifer were conducted using The Geochemist's Workbench 10.0.6. The examined processes encompassed dissolution of minerals forming the carbonate aquifer and Miocene evaporates overlying the Triassic aquifer as well as mixing of groundwater and surface water. © 2018 Polish Geological Institute. All rights reserved.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
In order to determine geochemical processes affecting chemical composition of groundwater in the Gliwice- Łabedy well-field area two research methods were applied. Chemical analysis allowed us to assess the quality of groundwater in the Triassic karst-fractured-porous aquifer of the southwestern part of the major groundwater basin no. 330. The chemical composition of groundwater is distinguished by spatial heterogeneity highlighted by higher mineralization and concentrations of individual ions in the western area. In addition, all samples collected in 2016 were analyzed for the δ35S and δ18O to identify sources of sulfates in the waters examined. The study revealed a different origin of these ions depending on location of the wells sampled. The results of chemical analysis and archival data allowed for application of geochemical modeling in identification of processes taking part in groundwater chemistry evolution. Simulations of processes controlling water chemistry within the Triassic aquifer were conducted using The Geochemist's Workbench 10.0.6. The examined processes encompassed dissolution of minerals forming the carbonate aquifer and Miocene evaporates overlying the Triassic aquifer as well as mixing of groundwater and surface water. © 2018 Polish Geological Institute. All rights reserved.
Witkowski, A. J.; Rubin, H.; Jakóbczyk-Karpierz, S.; Rubin, K.
International Multidisciplinary Scientific Geoconference, vol. 18, no. 1.2, 2018, ISSN: 13142704, (1).
@proceedings{2-s2.0-85058887192,
title = {Application of geochemical modeling for the identification of main processes affecting changes in the quality of groundwater in the Łazy bŁĘdowskie well field, Southern Poland},
author = { A.J. Witkowski and H. Rubin and S. Jakóbczyk-Karpierz and K. Rubin},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85058887192&doi=10.5593%2fsgem2018%2f1.2%2fS02.010&partnerID=40&md5=a68bd02817d464f31a51537f68e8cffb},
doi = {10.5593/sgem2018/1.2/S02.010},
issn = {13142704},
year = {2018},
date = {2018-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {18},
number = {1.2},
pages = {75-82},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {Łazy Błędowskie well field located in the area of the Upper Silesia, was established in 1959. It consisted of max. 22 wells abstracting water from the Triassic carbonate aquifer (Olkusz-Zawiercie major aquifer). This aquifer is additionally heavily drained by Zn-Pb ore mines. Due to the decreasing demand for water and the deterioration of its quality, wells were gradually excluded from operation and liquidated. Currently, only 2 wells are exploited, pumping approx. 11500 m3 /d. As a result of the overlapping impact of various factors (changes of the groundwater table related to Zn-Pb ore mining and intensive groundwater abstraction by well fields; impact of industrial areas and landfills; discharges of municipal and industrial sewage; as well as agricultural activity) there was a significant deterioration in the groundwater quality. Elevated values of total hardness, sulphates, manganese, iron, turbidity and occasionally mercury and lead were found. The PHREEQC software was used to identify the ongoing hydrogeochemical processes. The database for geochemical modeling of saturation indices for mineral phases consisted the results of 280 physicochemical analyzes of water from the Łazy Błędowskie well field. The analysis showed that the main processes forming the chemical composition of groundwater are dissolution of carbonates and oxidation of sulphides, and subsequent dissolution of oxidation products. There may also be a dedolomitization process. These processes are intensified as a result of water table fluctuation, and thus changes in the oxidation-reduction conditions. © 2018, International Multidisciplinary Scientific Geoconference. All rights reserved.},
note = {1},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
Łazy Błędowskie well field located in the area of the Upper Silesia, was established in 1959. It consisted of max. 22 wells abstracting water from the Triassic carbonate aquifer (Olkusz-Zawiercie major aquifer). This aquifer is additionally heavily drained by Zn-Pb ore mines. Due to the decreasing demand for water and the deterioration of its quality, wells were gradually excluded from operation and liquidated. Currently, only 2 wells are exploited, pumping approx. 11500 m3 /d. As a result of the overlapping impact of various factors (changes of the groundwater table related to Zn-Pb ore mining and intensive groundwater abstraction by well fields; impact of industrial areas and landfills; discharges of municipal and industrial sewage; as well as agricultural activity) there was a significant deterioration in the groundwater quality. Elevated values of total hardness, sulphates, manganese, iron, turbidity and occasionally mercury and lead were found. The PHREEQC software was used to identify the ongoing hydrogeochemical processes. The database for geochemical modeling of saturation indices for mineral phases consisted the results of 280 physicochemical analyzes of water from the Łazy Błędowskie well field. The analysis showed that the main processes forming the chemical composition of groundwater are dissolution of carbonates and oxidation of sulphides, and subsequent dissolution of oxidation products. There may also be a dedolomitization process. These processes are intensified as a result of water table fluctuation, and thus changes in the oxidation-reduction conditions. © 2018, International Multidisciplinary Scientific Geoconference. All rights reserved.
Sitek, S. S.; Jakóbczyk-Karpierz, S.
International Multidisciplinary Scientific Geoconference, vol. 18, no. 3.1, 2018, ISSN: 13142704, (1).
@proceedings{2-s2.0-85058879157,
title = {Occurrence and fate of trichloroethene and tetrachloroethene in carbonate aquifer, tarnowskie gÓry area (Southern Poland)},
author = { S.S. Sitek and S. Jakóbczyk-Karpierz},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85058879157&doi=10.5593%2fsgem2018%2f3.1%2fS12.070&partnerID=40&md5=6258315a26b7da44101e2a195c18f799},
doi = {10.5593/sgem2018/3.1/S12.070},
issn = {13142704},
year = {2018},
date = {2018-01-01},
urldate = {2018-01-01},
journal = {International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM},
volume = {18},
number = {3.1},
pages = {539-546},
publisher = {International Multidisciplinary Scientific Geoconference},
abstract = {Trichloroethene (TCE) and tetrachloroethene (PCE) have been detected in water of the Triassic carbonate aquifer in Tarnowskie Góry area since 1994. Since 2005, TCE and PCE in groundwater have been constantly monitored by the Voivodship Inspectorate for Environmental Protection in Katowice in 12 observation wells and pumping wells located in Tarnowskie Góry and outskirts of the city. After 24 years chlorinated solvents still pose a serious environmental risk and are responsible for closure of selected wells situated in Tarnowskie Góry as well as outside the city. In order to investigate the occurrence pattern and fate of these pollutants in carbonate aquifer, which is a strategic abundant reservoir of potable water for the western part of the Upper Silesian agglomeration, the extended field campaigns in 2010 and 2016 were carried out. The obtained results confirmed the assumption that the main source of the contamination coincides with industrial site in Tarnowskie Góry and provided information about spreading the contamination plume over 15 km in the west and southwest direction from the potential sources. Although the concentrations of TCE and PCE decrease with increasing distance from Tarnowskie Góry, the concentration of sum of TCE and PCE exceeded drinking limit 10 µg/dm3 in some wells outside the city. The major factors responsible for transport of TCE and PCE in carbonate aquifer are gradient of the water table, pumping rates of the wells, geological structure of the aquifer and location of the drainage mine galleries. Due to the oxidizing conditions in the aquifer the natural degradation of these constituents did not occurred, therefore, the daughter products of TCE and PCE in water samples were not found. © SGEM2018 All Rights Reserved.},
note = {1},
keywords = {},
pubstate = {published},
tppubtype = {proceedings}
}
Trichloroethene (TCE) and tetrachloroethene (PCE) have been detected in water of the Triassic carbonate aquifer in Tarnowskie Góry area since 1994. Since 2005, TCE and PCE in groundwater have been constantly monitored by the Voivodship Inspectorate for Environmental Protection in Katowice in 12 observation wells and pumping wells located in Tarnowskie Góry and outskirts of the city. After 24 years chlorinated solvents still pose a serious environmental risk and are responsible for closure of selected wells situated in Tarnowskie Góry as well as outside the city. In order to investigate the occurrence pattern and fate of these pollutants in carbonate aquifer, which is a strategic abundant reservoir of potable water for the western part of the Upper Silesian agglomeration, the extended field campaigns in 2010 and 2016 were carried out. The obtained results confirmed the assumption that the main source of the contamination coincides with industrial site in Tarnowskie Góry and provided information about spreading the contamination plume over 15 km in the west and southwest direction from the potential sources. Although the concentrations of TCE and PCE decrease with increasing distance from Tarnowskie Góry, the concentration of sum of TCE and PCE exceeded drinking limit 10 µg/dm3 in some wells outside the city. The major factors responsible for transport of TCE and PCE in carbonate aquifer are gradient of the water table, pumping rates of the wells, geological structure of the aquifer and location of the drainage mine galleries. Due to the oxidizing conditions in the aquifer the natural degradation of these constituents did not occurred, therefore, the daughter products of TCE and PCE in water samples were not found. © SGEM2018 All Rights Reserved.
2017
Jakóbczyk-Karpierz, S.; Sitek, S. S.; Jakobsen, R.; Kowalczyk, A.
In: Applied Geochemistry, vol. 76, pp. 168-181, 2017, ISSN: 08832927, (38).
@article{2-s2.0-85003914585,
title = {Geochemical and isotopic study to determine sources and processes affecting nitrate and sulphate in groundwater influenced by intensive human activity - carbonate aquifer Gliwice (southern Poland)},
author = { S. Jakóbczyk-Karpierz and S.S. Sitek and R. Jakobsen and A. Kowalczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85003914585&doi=10.1016%2fj.apgeochem.2016.12.005&partnerID=40&md5=28c231569e373260343f591badce2705},
doi = {10.1016/j.apgeochem.2016.12.005},
issn = {08832927},
year = {2017},
date = {2017-01-01},
urldate = {2017-01-01},
journal = {Applied Geochemistry},
volume = {76},
pages = {168-181},
publisher = {Elsevier Ltd},
abstract = {A multi-species, multi-stable-isotope approach (δ15NNO3; δ18ONO3; δ34SSO4; δ18OSO4; δ18OH2O and δ2HH2O) was used together with environmental tracers (Ar; Ne; CFC-11 and CFC-12) and geochemical modelling to characterize sources and processes controlling concentrations of NO3− and SO42- in groundwater of the carbonate aquifer Gliwice (southern Poland). The study area represents a strongly transformed environment with a range of human activities i.a. Agriculture, urbanization and industry. The δ15NNO3 and δ18ONO3 indicated that most samples contained NO3− of mixed sources: artificial fertilizers, municipal and industrial sewage, while very good correlation between NO3− and CFC-12 suggested that nitrate originated primarily from residential and industrial sewage. Conversely, isotopic composition of sulphate in groundwater suggested agriculture as well as oxidation of sulphides as dominant. The conclusion was supported by the comparison of CFCs and sulphate concentrations which revealed no relevant correlation. Geochemical modelling confirmed the presence of sulphate reduction in areas where isotopic analyses were not possible due to undetectable sulphate. Thus, the integrated application of stable isotopes, environmental tracers, groundwater chemistry and geochemical modelling shows a complex origin of groundwater pollution in the study area as well as variety of geochemical processes controlling chemistry of groundwater in a triple-porosity aquifer influenced by different types of human activity. © 2016 Elsevier Ltd},
note = {38},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
A multi-species, multi-stable-isotope approach (δ15NNO3; δ18ONO3; δ34SSO4; δ18OSO4; δ18OH2O and δ2HH2O) was used together with environmental tracers (Ar; Ne; CFC-11 and CFC-12) and geochemical modelling to characterize sources and processes controlling concentrations of NO3− and SO42- in groundwater of the carbonate aquifer Gliwice (southern Poland). The study area represents a strongly transformed environment with a range of human activities i.a. Agriculture, urbanization and industry. The δ15NNO3 and δ18ONO3 indicated that most samples contained NO3− of mixed sources: artificial fertilizers, municipal and industrial sewage, while very good correlation between NO3− and CFC-12 suggested that nitrate originated primarily from residential and industrial sewage. Conversely, isotopic composition of sulphate in groundwater suggested agriculture as well as oxidation of sulphides as dominant. The conclusion was supported by the comparison of CFCs and sulphate concentrations which revealed no relevant correlation. Geochemical modelling confirmed the presence of sulphate reduction in areas where isotopic analyses were not possible due to undetectable sulphate. Thus, the integrated application of stable isotopes, environmental tracers, groundwater chemistry and geochemical modelling shows a complex origin of groundwater pollution in the study area as well as variety of geochemical processes controlling chemistry of groundwater in a triple-porosity aquifer influenced by different types of human activity. © 2016 Elsevier Ltd
2016
Czekaj, J.; Jakóbczyk-Karpierz, S.; Rubin, H.; Sitek, S. S.; Witkowski, A. J.
Identification of nitrate sources in groundwater and potential impact on drinking water reservoir (Goczałkowice reservoir, Poland) Journal Article
In: Physics and Chemistry of the Earth, vol. 94, pp. 35-46, 2016, ISSN: 14747065, (19).
@article{2-s2.0-84966534225,
title = {Identification of nitrate sources in groundwater and potential impact on drinking water reservoir (Goczałkowice reservoir, Poland)},
author = { J. Czekaj and S. Jakóbczyk-Karpierz and H. Rubin and S.S. Sitek and A.J. Witkowski},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84966534225&doi=10.1016%2fj.pce.2015.11.005&partnerID=40&md5=da0090ddc4ab742d04447948c7cd6418},
doi = {10.1016/j.pce.2015.11.005},
issn = {14747065},
year = {2016},
date = {2016-01-01},
urldate = {2016-01-01},
journal = {Physics and Chemistry of the Earth},
volume = {94},
pages = {35-46},
publisher = {Elsevier Ltd},
abstract = {Goczałkowice dammed reservoir (area – 26 km2) is a strategic object for flood control in the Upper Vistula River catchment and one of the most important source of drinking water in the Upper Silesian Industrial Region (Southern Poland). Main aims of the investigation were identification of sources of nitrate and assessment of their significance in potential risk to groundwater quality. In the catchment area monitoring network of 22 piezometers, included 14 nested, have been installed. The significant spatial and seasonal differences in chemical composition between northern and southern part of the catchment were indicated based on the groundwater sampling conducted twice – in autumn 2011 and spring 2012. Maximum observed concentrations of nitrate were identified in northern part of the study area 255 mg/L as a results of inappropriate sewage management and agriculture activity. Results, based on the combines multi-scale hydrogeological and hydrochemical field studies, groundwater flow and transport modelling, dual stable isotope approach and geochemical modelling indicate mainly agriculture and inappropriate sewage water management as a sources of NO3− contamination of groundwater which moreover is affected by geochemical processes. In general, contaminated groundwater does not impact surface water quality. However, due to high concentration of nitrate in northern part a continues measurements of nitrogen compounds should be continued and used for reducing uncertainty of the predictive scenarios of the mass transport modelling in the study area. © 2015 Elsevier Ltd},
note = {19},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Goczałkowice dammed reservoir (area – 26 km2) is a strategic object for flood control in the Upper Vistula River catchment and one of the most important source of drinking water in the Upper Silesian Industrial Region (Southern Poland). Main aims of the investigation were identification of sources of nitrate and assessment of their significance in potential risk to groundwater quality. In the catchment area monitoring network of 22 piezometers, included 14 nested, have been installed. The significant spatial and seasonal differences in chemical composition between northern and southern part of the catchment were indicated based on the groundwater sampling conducted twice – in autumn 2011 and spring 2012. Maximum observed concentrations of nitrate were identified in northern part of the study area 255 mg/L as a results of inappropriate sewage management and agriculture activity. Results, based on the combines multi-scale hydrogeological and hydrochemical field studies, groundwater flow and transport modelling, dual stable isotope approach and geochemical modelling indicate mainly agriculture and inappropriate sewage water management as a sources of NO3− contamination of groundwater which moreover is affected by geochemical processes. In general, contaminated groundwater does not impact surface water quality. However, due to high concentration of nitrate in northern part a continues measurements of nitrogen compounds should be continued and used for reducing uncertainty of the predictive scenarios of the mass transport modelling in the study area. © 2015 Elsevier Ltd
2012
Jakóbczyk-Karpierz, S.; Kowalczyk, A.
In: Biuletyn - Panstwowego Instytutu Geologicznego, no. 451, pp. 91-100, 2012, ISSN: 08676143, (2).
@article{2-s2.0-84870719180,
title = {Advantages and constraints of groundwater dating using SF6 in carbonate aquifers on the example of MGWB Gliwice [Mozżliwości i ograniczenia zastosowania SF6 do oceny czasu przebywania wód w ośrodkach wȩglanowych na przykładzie GZWP Gliwice]},
author = { S. Jakóbczyk-Karpierz and A. Kowalczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84870719180&partnerID=40&md5=8f13d99465dccf38e8fefa1516e61da1},
issn = {08676143},
year = {2012},
date = {2012-01-01},
journal = {Biuletyn - Panstwowego Instytutu Geologicznego},
number = {451},
pages = {91-100},
abstract = {One of the most important issues in groundwater modelling is a validation process based on a comprehensive study of groundwater flow system. Groundwater dating, using environmental tracers like SF6, is a valuable tool for model verification. The paper describes preliminary results of SF6 application in the recognition of the MGWB Gliwice groundwater system. The aquifer represents a highly complex, triple-porosity hydrogeological system. The research, based on groundwater and surface water sampling carried out in 2010, revealed a generally high concentration of sulphur hexafluoride in water, ranging from 0.29 to 6.17 fmolL-1. In order to assess apparent groundwater age, selected lumped parameter models were applied, with a dispersion model chosen to fit best to the aquifer under investigation. The calculated residence time of tracer in the groundwater system is notably low and ranges generally from 5 to about 35 years, which suggests relatively short groundwater residence time in the aquifer.},
note = {2},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
One of the most important issues in groundwater modelling is a validation process based on a comprehensive study of groundwater flow system. Groundwater dating, using environmental tracers like SF6, is a valuable tool for model verification. The paper describes preliminary results of SF6 application in the recognition of the MGWB Gliwice groundwater system. The aquifer represents a highly complex, triple-porosity hydrogeological system. The research, based on groundwater and surface water sampling carried out in 2010, revealed a generally high concentration of sulphur hexafluoride in water, ranging from 0.29 to 6.17 fmolL-1. In order to assess apparent groundwater age, selected lumped parameter models were applied, with a dispersion model chosen to fit best to the aquifer under investigation. The calculated residence time of tracer in the groundwater system is notably low and ranges generally from 5 to about 35 years, which suggests relatively short groundwater residence time in the aquifer.
2011
Jakóbczyk-Karpierz, S.; Kowalczyk, A.
In: Biuletyn - Panstwowego Instytutu Geologicznego, no. 445 PART 1, pp. 217-226, 2011, ISSN: 08676143, (3).
@article{2-s2.0-80155214459,
title = {Application of geochemical modelling in assessing groundwater chemistry evolution in the gliwice łabedy intake area [Zastosowanie modelowania geochemicznego do oceny warunków kształtowania sie składu chemicznego wód podziemnych w rejonie ujecia gliwice łabedy]},
author = { S. Jakóbczyk-Karpierz and A. Kowalczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-80155214459&partnerID=40&md5=f3e8894d77d0bbc7e656107dc3448b89},
issn = {08676143},
year = {2011},
date = {2011-01-01},
journal = {Biuletyn - Panstwowego Instytutu Geologicznego},
number = {445 PART 1},
pages = {217-226},
abstract = {Paper presents results of spatial and temporal analysis of groundwater chemistry in Triassic fractured-karst-porous aquifer in the area of Gliwice łabdy well field for the years 1995-2010. Outcome of geochemical modelling was also described as a tool for quantitative assessment of geochemical processes active in that part of the carbonate aquifer. Spatial heterogeneity of groundwater chemistry within the study area is manifested mainly by higher mineralization and concentrations of major ions west of the trough filled with Miocene evaporite deposits, what reflects significant impact of Miocene sediments on the groundwater chemistry. Major processes controlling chemical composition of groundwater within the study area are dissolution of carbonates and evaporites, sulfides oxidation and denitrification. Redox processes play an important role particularly in the agricultural area where elevated concentrations of nitrates where observed. Geochemical modelling with Phreeqc allowed the authors to distinguish sources of sulphates in groundwater (sulphides oxidation and gypsum dissolution) in different parts of the investigated aquifer.},
note = {3},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Paper presents results of spatial and temporal analysis of groundwater chemistry in Triassic fractured-karst-porous aquifer in the area of Gliwice łabdy well field for the years 1995-2010. Outcome of geochemical modelling was also described as a tool for quantitative assessment of geochemical processes active in that part of the carbonate aquifer. Spatial heterogeneity of groundwater chemistry within the study area is manifested mainly by higher mineralization and concentrations of major ions west of the trough filled with Miocene evaporite deposits, what reflects significant impact of Miocene sediments on the groundwater chemistry. Major processes controlling chemical composition of groundwater within the study area are dissolution of carbonates and evaporites, sulfides oxidation and denitrification. Redox processes play an important role particularly in the agricultural area where elevated concentrations of nitrates where observed. Geochemical modelling with Phreeqc allowed the authors to distinguish sources of sulphates in groundwater (sulphides oxidation and gypsum dissolution) in different parts of the investigated aquifer.
Rubin, H.; Jakóbczyk-Karpierz, S.; Kowalczyk, A.; Rubin, K.
In: Biuletyn - Panstwowego Instytutu Geologicznego, no. 445 PART 2, pp. 603-614, 2011, ISSN: 08676143.
@article{2-s2.0-80055067017,
title = {Metals and metalloids in water from municipal wells and tap water in the area of racibórz [Wystepowanie metali i metaloidów w wodach z ujeć wodociagowych i z kranu u konsumenta na obszarze miasta racibórz]},
author = { H. Rubin and S. Jakóbczyk-Karpierz and A. Kowalczyk and K. Rubin},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-80055067017&partnerID=40&md5=e46405dc8ac8b7558cad8d0810d4c4ca},
issn = {08676143},
year = {2011},
date = {2011-01-01},
journal = {Biuletyn - Panstwowego Instytutu Geologicznego},
number = {445 PART 2},
pages = {603-614},
abstract = {Paper describes results of investigation on metals and metalloids concentrations in water from well fields and consumers' tap water in Racibórz. Concentrations above the maximum admissible level (MAL) were found for iron, manganese and lead in groundwater from municipal wells supplying citizens. Treatment processes lower elevated concentrations of investigated constituents below the MAL successfully. Concentrations of almost all investigated elements in tap water show increased maximum values with respect to water after treatment. In case of iron, nickel and lead, concentrations exceeding MAL were detected. Authors analyzed influence of different factors on occurrence of increased values of metals and metalloids in tap water. It was estimated that exposure of the consumers to iron is low and to nickel and lead is very low. Conclusions on measures to be taken to improve the drinking water quality in the area of Raciborz were presented.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Paper describes results of investigation on metals and metalloids concentrations in water from well fields and consumers' tap water in Racibórz. Concentrations above the maximum admissible level (MAL) were found for iron, manganese and lead in groundwater from municipal wells supplying citizens. Treatment processes lower elevated concentrations of investigated constituents below the MAL successfully. Concentrations of almost all investigated elements in tap water show increased maximum values with respect to water after treatment. In case of iron, nickel and lead, concentrations exceeding MAL were detected. Authors analyzed influence of different factors on occurrence of increased values of metals and metalloids in tap water. It was estimated that exposure of the consumers to iron is low and to nickel and lead is very low. Conclusions on measures to be taken to improve the drinking water quality in the area of Raciborz were presented.
2010
Jakóbczyk-Karpierz, S.; Kowalczyk, A.
In: Biuletyn - Panstwowego Instytutu Geologicznego, no. 442, pp. 79-84, 2010, ISSN: 08676143.
@article{2-s2.0-78650149465,
title = {Groundwater chemistry of the triassic carbonate aquifer in the bibiela well field area in view of geochemical modelling [SkŁad chemiczny wód podziemnych wȩglanowego kompleksu wodonośnego triasu w rejonie ujȩcia bibiela w świetle badań modelowych]},
author = { S. Jakóbczyk-Karpierz and A. Kowalczyk},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-78650149465&partnerID=40&md5=9a77df1b93ab9fc2562022fe20eb7849},
issn = {08676143},
year = {2010},
date = {2010-01-01},
journal = {Biuletyn - Panstwowego Instytutu Geologicznego},
number = {442},
pages = {79-84},
abstract = {The Bibiela well field is one of the biggest intakes in the Upper Silesian region, extracting groundwater from the Triassic carbonate aquifer. The paper describes groundwater chemistry based on over 5000 chemical analyses of water from 22 wells from the years of 1956-2009. Saturation conditions of water with respect to calcite, dolomite and gypsum were calculated by means of AquaChem software combined with Phreeqc. Chemical composition of considered groundwater shows spatial and temporal variability mostly due to complicated geology. Intensive groundwater exploitation caused water table lowering of about 70 m, what changed hydrogeochemical conditions and caused some processes to happen or intensify. The most probable process is calcite and dolomite dissolution but also dedolomitization due to inflow of water enriched with SO4 and Ca ions from the dissolution of gypsum.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The Bibiela well field is one of the biggest intakes in the Upper Silesian region, extracting groundwater from the Triassic carbonate aquifer. The paper describes groundwater chemistry based on over 5000 chemical analyses of water from 22 wells from the years of 1956-2009. Saturation conditions of water with respect to calcite, dolomite and gypsum were calculated by means of AquaChem software combined with Phreeqc. Chemical composition of considered groundwater shows spatial and temporal variability mostly due to complicated geology. Intensive groundwater exploitation caused water table lowering of about 70 m, what changed hydrogeochemical conditions and caused some processes to happen or intensify. The most probable process is calcite and dolomite dissolution but also dedolomitization due to inflow of water enriched with SO4 and Ca ions from the dissolution of gypsum.